高温超高压模拟实验研究--Ⅱ.高温高压下烷烃产物的演化特征   总被引：17，自引：1，他引：16  

姜峰  杜建国 《沉积学报》1998,16(4):145-148

对不成熟泥炭样品进行了高压（0.1～2 GPa) 、高温( 200 ℃～400 ℃）模拟实验,并对实验后样品的烷烃产物进行了分析。结果显示,同一压力条件下,温度升高,烷烃参数表现出更成熟的特征;温度较低时（200 ℃）,压力升高,烷烃参数表现出不成熟,温度较高时（400 ℃）,除个别特殊点之外,压力增大,烷烃参数愈来愈不成熟,说明温压条件都是影响有机质成熟的重要因素,压力的存在会抑制有机质的成熟作用。用模拟实验手段来探讨压力的作用和影响,具有重要的理论及实际意义。  相似文献   

New basin modelling results from the Polish part of the Central European Basin system: implications for the Late Cretaceous–Early Paleogene structural inversion     

M. Resak  M. Narkiewicz  R. Littke 《International Journal of Earth Sciences》2008,97(5):955-972

Combined subsidence and thermal 1D modelling was performed on six well-sections located in the north-western Mid-Polish Trough/Swell in the eastern part of the Central European Basin system. The modelling allowed constraining quantitatively both the Mesozoic subsidence and the magnitude of the Late Cretaceous–Paleocene inversion and erosion. The latter most probably reached 2,400 m in the Mid-Polish Swell area. The modelled Upper Cretaceous thickness did not exceed 500 m, and probably corresponded to 200–300 m in the swell area as compared with more than 2,000 m in the adjacent non-inverted part of the basin. Such Upper Cretaceous thickness pattern implies early onset of inversion processes, probably in the Late Turonian or Coniacian. Our modelling, coupled with previous results of stratigraphic and seismic studies, demonstrates that the relatively low sedimentation rates in the inverted part of the basin during the Late Cretaceous were the net result of several discrete pulses of non-deposition and/or erosion that were progressively more pronounced towards the trough axis. The last phase of inversion started in the Late Maastrichtian and was responsible for the total amount of erosion, which removed also the reduced Upper Cretaceous deposits. According to our modelling results, a Late Cretaceous heat-flow regime which is similar to the present-day conditions (about 50 mW/m²) was responsible for the observed organic maturity of the Permian-Mesozoic rocks. This conclusion does not affect the possibility of Late Carboniferous–Permian and Late Permian–Early Triassic thermal events.  相似文献   

A neutron diffraction study of alkali cation migration in montmorillonites     

D. Gournis  A. Lappas  M. A. Karakassides  D. Többens  A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58

Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.  相似文献   

基于EOF分析对南海西北海域水体光谱特性的研究   总被引：1，自引：0，他引：1  

付东洋  黄宇业  刘大召  廖珊  余果  张小龙 《海洋学报(英文版)》2020,39(7):107-114

This study presents an analysis of the spectral characteristics of remote sensing reflectance(R_(rs)) in northwestern South China Sea based on the in situ optical and water quality data for August 2018.R_(rs)was initially divided into four classes,classes A to D,using the max-classification algorithm,and the spectral properties of whole R_(rs) were characterized using the empirical orthogonal function(EOF) analysis.Subsequently,the dominant factors in each EOF mode were determined.The results indicated that more than 95% of the variances of R_(rs) are partly driven by the back-scattering characteristics of the suspended matter.The initial two EOF modes were well correlated with the total suspended matter and back-scattering coefficient.Furthermore,the first EOF modes of the four classes of R_(rs)(A-D R_(rs)-EOF_1) significantly contributed to the total variances of each R_(rs) class.In addition,the correlation coefficients between the amplitude factors of class A-D R_(rs)-EOF_1 and the variances of the relevant water quality and optical parameters were better than those of the unclassified ones.The spectral shape of class AR_(rs)-EOF_1 was governed by the absorption characteristic of chlorophyll a and colored dissolved organic matter(CDOM).The spectral shape of class B R_(rs)-EOF_1 was governed by the absorption characteristic of CDOM since it exhibited a high correlation with the absorption coefficient of CDOM(a_g(λ)),whereas the spectral shape of class C R_(rs)-EOF_1 was governed by the back-scattering characteristics but not affected by the suspended matter.The spectral shape of class D R_(rs)-EOF_1 exhibited a relatively good correlation with all the water quality parameters,which played a significant role in deciding its spectral shape.  相似文献   

海洋生物-光学算法研究──南黄海叶绿素浓度的估算     

傅克忖  曾宪模  李宝华  曾晓起  荒川久幸 《海洋与湖沼》1997,28(3):238-244

根据１９９５年９月中日合作南黄海现场观测资料，对南黄海生物－光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素α对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。  相似文献   

有风浪太湖水体的光照传输模式   总被引：8，自引：0，他引：8       下载免费PDF全文

蔡启铭  杨平 《海洋与湖沼》1993,24(3):286-293

根据辐射传输方程的近似解方法和光照传输的累加原理,建立了包括水面风浪效应、水中悬浮粒多次散射和底泥反射的垂直分层水体的光照传输数值模式。利用该模式和太湖悬浮粒实测资料,计算和讨论了太湖水体中光照随水深的变化以及悬浮粒浓度、风浪和太阳高度的影响。结果表明,悬浮粒的多次散射所形成的漫射光是湖水中光照不可忽视的重要部分。在水体的下层,漫射光甚至是光照的主要构成部分。风浪对水中光照的影响则主要在天顶角大于70°时才明显地表现出来,此时风浪水体对太阳直接辐射和全辐射的反射率比平静水面都有明显的减小。  相似文献   

海洋生物-光学算法研究──南黄海叶绿素浓度的估算     

傅克忖  曾宪模  李宝华  曾晓起  荒川久幸 《海洋与湖沼》1997,28(3):238-244

根据1995年9月中日合作南黄海现场观测资料，对南黄海生物一光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素a浓度对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。  相似文献   

赤潮生物种类特征光谱获取技术   总被引：1，自引：0，他引：1  

范学炜  张汉德 《海洋科学进展》2002,20(2):83-90

较为系统地研究了赤潮生物水体反射率曲线获取方法。通过对 2类反射率反演方法得出的反射率曲线与实际反射率曲线进行比较 ,得出在不具备大气环境参数的情况下 ,经验线性法的反演结果与实际反射率曲线最接近的结论 ,并进一步对正常海水和赤潮生物水体的光谱特性进行分析 ,提取出赤潮生物水体的特征光谱。这是进行赤潮监测和识别的重要前提  相似文献   

Sources and hydrothermal alteration of organic matter in Quaternary sediments: A synthesis of studies from the Central Gulf of California     

Bernd R. T. Simoneit 《Marine and Petroleum Geology》1986,3(4)

Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone.  相似文献   

Microphytobenthos vertical migratory photoresponse as characterised by light-response curves of surface biomass     

Joo Serdio  Helena Coelho  Snia Vieira  Snia Cruz 《Estuarine, Coastal and Shelf Science》2006,68(3-4):547

The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (F_o); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m⁻² s⁻¹, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by F_o or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m⁻² s⁻¹, maximum values under 100–250 μmol m⁻² s⁻¹, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring F_o or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments.  相似文献